In the waterborne surfactant spectrum, the "acetylenic-alcohol modified silicone Gemini (dual-structure)" and "100% active polysiloxane copolymer backbone" jointly dictate packing compactness at air-liquid interface, dynamic surface tension (DST) drop speed, and the "breaks foam but makes none" boundary under high shear (spray/roll). Conventional polyether-modified silicone wetters pull ST to 25-28mN/m but AB linear structure stabilizes foam badly—formulators must add defoamer, which then hurts gloss/causes craters; plain acetylenediol (e.g., TMDE) has good DST but static ST ~30mN/m, powerless on PP/PE/fluorinated substrates. As waterborne industrial paint, flexo/gravure ink, and synthetic-leather release paper demand "0.1% ST <23mN/m, non-foaming, anti-crater, flow-promote, 0.1-1.0% dose, no clarity loss," sourcing a pale-yellow transparent, 20-60cp, RI 1.440-1.450, 25kg/200kg drum, 24-month RT product has become the core gap for domestic waterborne non-foam wetter localization.
Addressing this "non-foam strong-wet" pain point,
Anhui IOTA Silicone Oil Co., Ltd. (IOTA) officially launches
Non-Foaming Defoaming Wetting Agent IOTA-4100 (acetylenic-alcohol modified silicone Gemini surfactant, specially modified polysiloxane copolymer). Characterized by "pale-yellow transparent, 100% active, 25℃ visc 20-60cp, RI 1.440-1.450, 0.1% aq ST <23mN/m, dose 0.1-1.0%, fits waterborne PU/acrylic/epoxy, spray/high-speed-roll/hard-wet substrates, 25kg PE/200kg iron drum, sealed RT 24 months," and backed by "acetylenic Gemini compact + siloxane low-ST + unstable-foam puncture," it serves as the "wetting anchor" for waterborne coatings/inks/synthetic-leather release.
Molecular Architecture: Acetylenic Gemini Compact + Siloxane Low-ST + Air-Liquid Puncture 3D Logic
The core competitiveness of IOTA-4100 stems from its "short polydimethylsiloxane backbone grafted with acetylenic alcohol (–C≡C–CH(OH)–) side groups forming Gemini symmetric dual-head/dual-tail":
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Acetylenic Gemini Compact: Acetylene bond rigidly links two hydroxyl heads and two siloxane/alkyl tails—low molecular freedom, small size (Gemini MW hundreds vs linear polyether-silicone >1000), migrates from bulk to fresh interface an order faster; DST drops in millisecond scale, solving "droplet in flight no time to lower ST → crater on landing" in spray/roll.
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Siloxane Low Static ST: Short siloxane chain gives intrinsic low surface energy (pure PDMS ~21mN/m); 0.1% presses waterborne system ST <23mN/m, below critical of PP(29)/PE(31)/fluorinated(18-22)—wet film auto-spreads.
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Gemini Unstable-Foam: Two heads pack tight at air-liquid but don't form elastic stabilizing film like linear polyether-silicone; acetylenic end punctures microbubble apex (needle-balloon mechanism), merges and breaks existing bubbles—"self non-foaming + slight co-defoam", drops extra defoamer from formula.
Performance Leap: From "Wet-Must-Foam" to "Non-Foam Wet Anti-Crater"
Incorporating IOTA-4100 enables qualitative leaps:
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Waterborne Industrial Spray: Machinery/auto parts PU/acrylic spray, 0.3-0.6% kills fish-eye on PP/zinc-plated oily spots, foam gain negligible at >2000rpm disperse + atomize, 60° gloss >90%.
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Flexo/Gravure Ink: 0.1-0.5% in PE/PP film ink—DST-wet stops dot shrink/flying ink, no foam overflow in blade circulation 8h.
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Synthetic Leather Release: 0.2-0.8% before PU/PVC coat on release paper—resin fills paper micropores, no edge-retract, uniform peel, no speck on laminated leather.
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Waterborne Epoxy Floor: Self-leveling on damp concrete, 0.5% promotes flow while killing trowel air bubbles, cured no pinhole cluster.
Application Penetration: From Industrial Spray to Release Paper
IOTA-4100 covers sectors triply sensitive to "low ST + non-foam + dynamic wet":
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Waterborne Coatings: Industrial, wood, architectural, machinery (PP/metal/composite hard-wet).
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Printing Inks: Waterborne gravure/flexo, film print, foil print.
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Synthetic Leather: Release-paper wetting, PU/PVC topcoat.
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Electronic & Adhesive: Waterborne PSA, functional coating high-precision slot die.
IOTA Technical Guide: 0.1-1.0% Post-Add, No Hot Premix
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Addition: Recommend post-add at let-down stage, 0.1-1.0% on total formula; high-solid/high-visc take upper, low-energy substrate (PP/fluoro) 0.5-1.0% pre-trial.
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Dilution: 100% active straight-in; if predilute, use glycol-monobutyl ether/water (1:1) or IPA 5-10×, avoid pure-water long storage phase split.
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Compatibility: Homogeneous in PU/acrylic/epoxy, no haze/no oil-float; clearcoat pre-test transparency (usually <1% no gloss/haze impact).
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Taboo Red Line: Avoid long high-temp cook with strong acid/base/high-active curative—acetylenic OH may dehydrate under strong base, siloxane hydrolyze under strong acid; no direct high-conc co-heat with organotin/Zr catalysts; shake before use (slight turbid at low temp, clears at 25℃).
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Storage: 25kg PE/200kg iron drum; sealed cool (<35℃) RT; shelf 24 months, retest appearance/ST/visc and extend if qualified; non-haz general chemical, ventilate avoid long aerosol inhale.
Industry experts note that under VOC caps driving "water-replaces-oil" and waterborne ink/leather lines speeding to 300m/min, single-function wetters can't hold "dynamic wet + non-foam + anti-crater" triangle—acetylenic-modified silicone Gemini is upgrading from "Evonik Tego® Twin 4000 / BYK-349 import followers" to "waterborne high-speed construction reference additive." IOTA-4100, with its "100% active + 0.1% ST <23mN/m + 20-60cp + Gemini non-foam + 24-month" hard metrics,
fills the domestic supply chain gap for non-foaming defoaming wetting agents in waterborne PU/acrylic/epoxy and ink/release-paper fields, providing a mass-producible path to replace imported Tego Twin 4100, BYK-348 for downstream paint/ink/leather makers. This confirms domestic waterborne additives are advancing steadily along "polyether-silicone (foam-stable) → acetylenediol (ST not low enough) → acetylenic silicone Gemini (non-foam + <23mN/m)," with growing technical say in waterborne high-speed-coat key additives.