In the synthesis of phenyl silicone oil, silicone resin, liquid crystal materials, pharmaceutical intermediates, and optoelectronic functional molecules, obtaining structurally defined, molecular-weight-certain, phenyl-density-controllable silane precursors is the core proposition shared by labs and production lines. Ordinary phenylchlorosilane monomers hydrolyze violently with many byproducts and difficult-to-remove halogen residues; fully phenylated condensates have broad molecular weight distribution and poor batch repeatability; low-phenyl disiloxanes lack refractive index and heat resistance for high-end optics and pharma carriers. With fine chemicals and silicone materials demanding "defined structure, high purity, narrow distribution, high refractive index" precursors, finding a "tetraphenyl-surrounded, dimethyl-terminated, symmetric disiloxane, clear melting point, easy to purify" intermediate has become a key synthesis issue.
Addressing this,
Anhui IOTA Silicone Oil Co., Ltd. officially launches
Dimethyltetraphenyldisiloxane IOTA 259 (1,3-dimethyl-1,1,3,3-tetraphenyldisiloxane). Characterized by "CAS 807-28-3; formula C₂₆H₂₆OSi₂; EINECS 212-361-3; mp 46–49℃; bp 215℃; density 1.076; refractive index 1.598; flash point 193℃; purity 98%; packaging 10/25/50kg", backed by "symmetric tetraphenyl + dimethyl termini + defined MW + high RI", it serves as the "nucleating choice" for silicone materials and fine synthesis,
achieving the leap from "chlorosilane hydrolysis with heavy byproducts" to "tetraphenyl disiloxane high-purity crystalline new nucleus".
System Positioning: Symmetric Tetraphenyl Disiloxane vs. Phenylchlorosilane/Hexaphenyldisiloxane
IOTA 259 belongs to the symmetric diaryldisiloxane family, distinct from halo-substituted monomers and fully phenylated disiloxanes. Phenylchlorosilane hydrolyzes violently with HCl release and persistent halogen residues. Hexaphenyldisiloxane has excessive phenyl density and too high melting point. IOTA 259, with "tetraphenyl surround" — two phenyls on each silicon — provides high refractive index (1.598) and heat-resistant backbone, while dimethyl termini lower the mp to 46–49℃ (meltable solid near room temperature), balancing reactivity and handling convenience, with no halohydrosis risk.
Molecular Architecture: C₂₆H₂₆OSi₂ + Tetraphenyl Surround + Dimethyl Termini + Symmetric Disiloxane
The core design of IOTA 259 comes from 1,3-dimethyl-1,1,3,3-tetraphenyldisiloxane:
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Tetraphenyl Surround: Four phenyls (C₆H₅)₄ across two silicons deliver extremely high refractive index (1.598, near optical glass), excellent thermal/oxidative resistance, and compatibility with phenyl rubber/resin; steric hindrance of four phenyls protects the central Si-O-Si bond, enhancing thermal stability.
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Dimethyl Termini: One methyl on each silicon (CH₃)₂ reduces molecular symmetry and packing density, precisely setting mp at 46–49℃ — stable as solid at room temperature (avoiding low-MW liquid volatilization) yet meltable with slight heating for feeding, offering a friendly operation window.
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Symmetric Disiloxane Backbone: -Si(CH₃)(C₆H₅)₂-O-Si(CH₃)(C₆H₅)₂- linear central oxygen bridge connects two equivalent silicon centers with defined MW (410.67), avoiding broad MWD of condensates and enabling precise stoichiometric control as intermediate.
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Clear Physicochemical Baseline: Boiling point 215℃ defines distillation purification window; density 1.076 eases dosing; flash point 193℃ indicates low fire risk at room temperature; purity 98% meets pharma and material intermediate requirements.
Performance Leap: From "Halogen Monomer Byproducts" to "High-Purity Tetraphenyl Intermediate Control"
Introducing IOTA 259 brings the following improvements:
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Defined Structure: Certain MW (C₂₆H₂₆OSi₂), avoiding broad MWD of condensed polymers for precise molar dosing.
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High-RI Platform: Refractive index 1.598 provides a high-refractive starting node for phenyl silicones, forming a gradient matrix with IOTA 232 (1.500) and IOTA 2238 (1.4485).
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Low-Melt Handling: Mp 46–49℃; solid at room temperature prevents volatilization, melts with mild heating for easy weighing and melt feeding.
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Thermal Safety: Boiling point 215℃, flash point 193℃, high operational safety; tetraphenyl backbone resists heat and oxidation.
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High Purity Low Impurity: Purity 98% fits pharma intermediates, material intermediates, and other impurity-sensitive scenarios.
Application Penetration: From Pharma Intermediates to Optoelectronic Materials
IOTA 259 covers multiple synthesis and fine-chemical scenarios:
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Pharmaceutical Intermediates: As silylation protecting group or phenylsilanol equivalent for drug molecule modification and API synthesis.
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Material Intermediates: Structural unit for liquid crystal materials, optoelectronic functional molecules, and high-refractive coatings.
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Fine Chemicals: Chemical reagent, standard reference, model compound for silicon chemistry teaching and research.
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Phenyl Silicone Synthesis: Copolymerizes with D4/DMC or chlorosilanes to synthesize high-refractive phenyl silicone oil and resin; acts as chain terminator to tune polymer phenyl density.
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Grignard/Coupling: Under anhydrous and oxygen-free conditions, participates in C-Si bond formation with Grignard reagents, organolithium, and aryl halides.
IOTA Technical Guide: Mild Heat to Melt, Anhydrous and Oxygen-Free
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Application: As intermediate, heat above 50℃ for melt addition, or dissolve in toluene, xylene, THF for feeding. With Grignard, organolithium, aryl halides, use anhydrous and oxygen-free conditions. Dosage by molar ratio of target product. Fix ratio by target molecular weight, phenyl density, and cure speed through trials.
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Compatibility: Siloxane bonds may rearrange under strong acid/base; avoid prolonged coexistence. Separate from peroxides and strong oxidants.
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⚠️ Taboo: Flash point 193℃ is relatively high but keep from open flame and high heat; reseal after use to prevent moisture (solid form but prolonged exposure may absorb moisture or contaminants); strictly anhydrous/oxygen-free for Grignard/organolithium reactions; wear protective gloves and goggles.
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Storage: 10kg, 25kg, 50kg packaging. Store in cool dry place, sealed from moisture. Alongside IOTA R05 (diphenylsilanediol, fiber/plastic, RTV structure control) as phenylsilicone intermediates, IOTA 259 is a symmetric tetraphenyl disiloxane, 10–50kg drum, mp 46–49℃; contrasting with IOTA 232 (phenyl hydride bis-terminator, liquid, addition crosslinker), it forms a "intermediate vs. crosslinker" complementary matrix.
Industry Insight: The core value of dimethyltetraphenyldisiloxane lies in "tetraphenyl surround for high RI and heat resistance, dimethyl termini for low-melt handling, symmetric disiloxane for defined molecular weight". IOTA 259, with "CAS 807-28-3, C₂₆H₂₆OSi₂, mp 46–49℃, bp 215℃, density 1.076, RI 1.598, flash 193℃, purity 98%, 10/25/50kg" hard parameters,
fills the nucleating link of domestic symmetric tetraphenyl disiloxane in pharma intermediates, material intermediates, and fine synthesis. For synthesis labs and silicone manufacturers, it upgrades along the path of "phenylchlorosilane hydrolysis → phenylalkoxysilane → tetraphenyl disiloxane high-purity crystal", reducing halogen residues and byproduct risks while raising purity and process safety premium.